## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Synthesis of Bicyclic Ortho Esters by Epoxy Ester Rearrangements and Study of Their Ring-Opening Reactions
✍ Scribed by Wipf, Peter; Aslan, Diana C.
- Book ID
- 120085064
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 107 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Ring‐opening reactions of 3‐arylaziridine‐2‐carboxylic esters with various nucleophiles are described. Racemic methyl 3‐(4‐methoxyphenyl)‐, 3‐phenyl‐ and 3‐(4‐nitrophenyl)aziridine‐2‐carboxylate (1a, 1b and 1c, respectively) were selected as substrates. In the absence of acid, no ring o
## Abstract The exocyclically unsaturated conjugated keto esters **10**, obtained __via__ a __Claisen__ ortho ester rearrangement of the allylic hydroxy ketones **9**, were either directly hydrogenated or partially isomerized into the endocyclically unsaturated tetrasubstituted didehydrojasmonoid i