Synthesis of benzotristriazole. 4-nitrobenzo[1,2-d:3,4-d′] bistriazole and 4,4′-dicarboxy-5,5′-1H-1,2,3-triazole
✍ Scribed by V. A. Samsonov; L. B. Volodarskii; V. L. Korolev; G. Kh. Khisamutdinov
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 230 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-3122
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📜 SIMILAR VOLUMES
In the molecule of the title compound, C 5 H 7 N 7 S, the essentially planar triazole ring and the 4-amino-5-mercapto-1,2,4-triazole moiety make a dihedral angle of 70.97 (5) . In the crystal structure, weak intermolecular N-HÁ Á ÁN and N-HÁ Á ÁS hydrogen bonds stabilize the packing.
In the title compound, C 12 H 12 N 6 O 2 S, the thiophene ring is disordered equally over two positions, corresponding to rotation of approximately 180 about the C-C single bond. The central triazole ring has substituents at the 1-, 3-, 4-and 5positions. Intermolecular C-HÁ Á ÁN and C-HÁ Á ÁO intera