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Synthesis of Beltenes by Reactions of 5,6,11,12-Tetradehydrodibenzo[a,e]cyclooctene with [CpCo(CO)2] Derivatives

✍ Scribed by Björn Hellbach; Frank Rominger; Rolf Gleiter


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
214 KB
Volume
43
Category
Article
ISSN
0044-8249

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A new method for constructing 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene is described on the basis of one-pot double elimination protocol. The target molecule, which is the smallest cyclophane with alternate arylene-ethynylene linkage, is synthesized in 61 % yield through oxidative dimerization o