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Synthesis of barene alcohols and cleavage of the C-C bond in them under the influence of sodium amide

✍ Scribed by L. I. Zakharkin; A. V. Kazantsev

Book ID
112420081
Publisher
Springer
Year
1966
Tongue
English
Weight
198 KB
Volume
15
Category
Article
ISSN
1573-9171

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In the photochemical reaction of anthraquinone triplet with both tertiary alcohols and tert.Bu-benzene in C6H6 are also broken, yielding CH at A.2334 nm not only C-H (or O-H) bonds but C-C bonds 3' and R1C(R2)OH (or C6HSC(CH3)2)radicals, at room temperature. Wagner and Puchalski have shown, that in