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Synthesis of Ba0.6K0.4BiO3 and BaPb0.75Bi0.25O3 superconductors by sol-gel process

✍ Scribed by G.V.Rama Rao; U.V. Varadaraju; S.L. Mannan

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
190 KB
Volume
235-240
Category
Article
ISSN
0921-4534

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✦ Synopsis

We have synthesised Bao.6Ko.4BiO3 (BKB) and BaPbl-xBixO3-y compounds by sol-gel process. IR spectra of gels indicated the bridging type of bonding between metal carboxylates leading to the formation of homogeneous gels. BKB and BaPbo.75Bio.2503 compounds exhibited sharp superconducting transitions from R-T and~-T measurements indicating excellent homogeneity of the samples:

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