𝔖 Bobbio Scriptorium
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Synthesis of axinastatins 2 – 5

✍ Scribed by Oliver Mechnich; Horst Kessler


Book ID
103410632
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
169 KB
Volume
37
Category
Article
ISSN
0040-4039

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## Abstract Methyl 2,5‐dideoxy‐5‐iodo‐3‐__O__‐pivaloyl‐D‐__erythro__‐pentofur‐anoside (5) was synthesized from 2‐deoxy‐D‐ribose and treated with triethyl phosphite to give the phosphonate 6. Reaction of 6 with silylated 2,4‐dihydroxypyrimidine 7 in the presence of trimethylsilyl trifluoromethanesul