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Synthesis of aryl-β-chlorovinyl ketones

✍ Scribed by A. N. Nesmeyanov; N. K. Kochetkov; M. I. Rybinskaya

Book ID: 112491644
Publisher: Springer
Year: 1954
Tongue: English
Weight: 204 KB
Volume: 3
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf01172711

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## Abstract Aryl β‐chlorovinyl ketones react with the methyl group of 2,6‐di‐__tert__‐butyl‐4‐methylpyrylium perchlorate in the presence of pyridine to yield doubly vinylogous 4__H__‐pyrones **3**. Only one configuration and conformation from the eight possible structures appears to be present acco