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Synthesis of Aryl Azide Analogues of Insect Juvenile Hormones as Reagents for the Photoaffinity Labeling of Juvenile Hormone Binding Proteins

✍ Scribed by Stupp, Hans-Peter ;Peter, Martin G.

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 549 KB
Volume: 1987
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.198719870329

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✦ Synopsis

The azidophenyl 6.7-epoxygeranyl ethers ruc4c and ruc-rld and the azidobenzoate ruc-6 were synthesized pAzidophenyl 6,7epoxygeranyl ether (rac4c) shows a high afhity to the juvenile hormone binding protein of the migratory locust, Locusro migraioria. Fast photolysis is observed upon irradiation at 254 nm and at 300 nm. It is proposed that ruc4c is useful as a new reagent for the study of juvenile hormone binding proteins of insects in which the natural hormone is 1 a. The synthesis and binding prop erties of thc aryl ketone roc-4e and the vinyl ketone roc-7 are described also.

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