Synthesis of aromatic ketones by acylation of aryl ethers with carboxylic anhydrides in the presence of zeolite H-β (H-BEA) in the absence of solvent
✍ Scribed by Keith Smith; Zhao Zhenhua; Philip K.G. Hodgson
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 96 KB
- Volume
- 134
- Category
- Article
- ISSN
- 1381-1169
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The stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW 12 O 40 ), was found to be an effective catalyst (3 mol%) for the solvent-free Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the presence of trifluoroacetic anhydride under mild reaction conditions.
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