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Synthesis of Aromatic Aldehydes by a Fast Method Involving Kornblum's Reaction

✍ Scribed by Bratulescu, George


Book ID
118173421
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
101 KB
Volume
38
Category
Article
ISSN
0039-7911

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The reaction of aromatic aldehydes with methyl thiocyenate in the presence of tributylphosphine afforded both S-methyl thiobenzoates and phenylacetonitriles via a novel disproportionation pathway involving carbon-carbon bond formation.