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Synthesis of aristoteline-type alkaloids. Part II. The structure of neohobartine, a side product of the hobartine-aristoteline transformation

✍ Scribed by Hans-Jürg Borschberg


Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
255 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The structure of neohobartine (3), a side product of the acid‐catalyzed conversion of (−)‐hobartine (1) into (+)‐aristoteline (2), has been elucidated by spectroscopic methods. Possible mechanistic pathways leading to its 1‐azaaadamantane skeleton are discussed.