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Synthesis of Aristotelia-Type Alkaloids.. Part IV. Synthesis of (±)-aristoserratine

✍ Scribed by Stefan Burkard; Hans-Jürg Borschberg

Publisher
John Wiley and Sons
Year
1989
Tongue
German
Weight
661 KB
Volume
72
Category
Article
ISSN
0018-019X

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✦ Synopsis

Part 111: [I]. ') Hobartine (4) has been synthesized by others in racemic [3] [4] and optically activc form [5] Sc hemr 4 CHO dC? dC> OK$ p-M BS p-M BS H 15 18 17 R=CH, Reagents: a) 1. 2 equiv. BuLi, 2. p-methoxybenzenesulfonyl chloride; b) CH,N2; c) DIBAH, -70". ' ) 7,

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