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Synthesis of anti-1,3-Diols through RuCl3/PPh3-Mediated Hydrogenation of β-Hydroxy Ketones: An Alternative to Organoboron Reagents

✍ Scribed by Christophe Roche; Olivier Labeeuw; Mansour Haddad; Tahar Ayad; Jean-Pierre Genet; Virginie Ratovelomanana-Vidal; Phannarath Phansavath

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
796 KB
Volume
2009
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Synthesis of anti-1
ChemInform Abstract: Synthesis of anti-1,3-Diols Through RuCl3/PPh3-Mediated Hydrogenation of β-Hydroxy Ketones: An Alternative to Organoboron Reagents.
✍ Christophe Roche; Olivier Labeeuw; Mansour Haddad; Tahar Ayad; Jean-Pierre Genet 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 30 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Highly Stereoselective and Efficient Add
Highly Stereoselective and Efficient Addition of Organocerium Reagents to syn-β-Alkyl-β-hydroxy-α-methyl Ketones by Way of Their Titanium Alkoxides − Synthesis of Complex 1,3-Diol Units with Three Stereodefined Centres
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A highly efficient and stereoselective technique for additions to syn-β-alkyl-β-hydroxy-α-methyl ketones is now available. The methodology is based on the conversion of the starting material into a trichlorotitanium alkoxide derivative, which is able to assume a stable cyclic arrangement exhibiting