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Synthesis of Anomeric Sulfimides and Their Use as a New Family of Glycosyl Donors

✍ Scribed by Florence Chéry; Stéphanie Cassel; Hans Peter Wessel; Patrick Rollin

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
396 KB
Volume
2002
Category
Article
ISSN
1434-193X

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✦ Synopsis

We introduce a convenient synthesis of anomeric sulfimides, the ability of which to act as glycosyl donors has been tested with various thiophilic reagents and acceptors.

📜 SIMILAR VOLUMES

ChemInform Abstract: First Synthesis of
ChemInform Abstract: First Synthesis of Anomeric Sulfimides — Efficient Glycosyl Donors.
✍ S. CASSEL; I. PLESSIS; H. P. WESSEL; P. ROLLIN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

First Synthesis of Anomeric Sulfimides -Efficient Glycosyl Donors. -Carbohydrate-derived sulfimides of type (III) are efficiently prepared by reaction of the corresponding thioglycosides with chloramine T. They are investigated as glycosyl donors with a variety of alcohols. In several cases the ano