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Synthesis of anhydride precursors of the environment-sensitive fluorophores 4-DMAP and 6-DMN

✍ Scribed by Sainlos, Matthieu; Imperiali, Barbara


Book ID
109946372
Publisher
Nature Publishing Group
Year
2007
Tongue
English
Weight
168 KB
Volume
2
Category
Article
ISSN
1750-2799

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In(C 6 F 5 ) 3 Β΄CH 3 CN and In(C 6 F 5 ) 3 Β΄glyme were synthesized from InCl 3 and Cd(C 6 F 5 ) 2 in CH 3 CN or glyme in 43% and 35% yield, respectively. Replacement of CH 3 CN or (C 2 H 5 ) 2 O by DMAP yielded the corresponding 1 : 1-adduct. [PNP][In(C 6 F 5 ) 4 ] was best prepared from the corres