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Synthesis of and Olefin Polymerization Using Tethered, a nsa -Metallocene Complexes

✍ Scribed by Tian, Jun; Soo-Ko, Young; Metcalfe, Robert; Feng, Yuding; Collins, Scott

Book ID
120014065
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
44 KB
Volume
34
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Synthesis of Silica-Supported Metallocen
Synthesis of Silica-Supported Metallocene Catalysts for Olefin Polymerization
✍ FrΓ©dΓ©ric Bortolussi; Jean-Pierre Broyer; Roger Spitz; Christophe Boisson πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 124 KB

## Abstract Four supported metallocene catalysts were synthesized directly on silica [Si(CpZrCp), Si(CpZrInd), Si(IndZrCp), and Si(IndZrInd)]. The first ligand was chemically tethered to silica (internal ligand) while the second was free from silica (external ligand). The polymerization of ethylene