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Synthesis of Analogues of Brassinosteroids from Chenodeoxycholic Acid

✍ Scribed by Roxana Pérez Gil; Martín Andrés Iglesias Arteaga; Carlos Pérez Martínez; Francisco Coll Manchado; Danahe Coll García; Arístides Rosado

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
139 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis

The synthesis and spectroscopic characterization of two new hydroxylated cholanic side chain, an A/B ring cis-junction and oxygenated functions in C-7 is described. bioactive analogues of brassinosteroids with a 24-

📜 SIMILAR VOLUMES

Stereoselective Introduction of Steroid
Stereoselective Introduction of Steroid Side Chains. Synthesis of Chenodeoxycholic Acid
✍ Peter M. Wovkulich; Andrew D. Batcho; Milan R. Uskoković 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 260 KB

## Abstract A new short route to chenodeoxycholic acid has been developed. The synthesis is based on the stereoselective introduction of the steroidal side chain __via__ an ene reaction of methyl acrylate and a (17Z)‐ethylidene steroid prepared from androstenedione.