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Synthesis of an optically active poly(aryleneethynylene) containing extended conjugation in the repeat unit

✍ Scribed by Liang Ma; Qiao-Sheng Hu; Lin Pu


Book ID
108038456
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
187 KB
Volume
7
Category
Article
ISSN
0957-4166

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Palladium-catalyzed polycondensation between 2,5-diiodo-3-hexylthiophene I-Th(Hex)-I with mixtures of p-diethynylbenzene HCϡC-Ph-CϡCH and ␣,diethynylalkane HCϡC(CH 2 ) l CϡCH (l ϭ 3 or 8) gives poly(aryleneethynylene) PAE-type copolymers [CϡC(CH 2 ) l CϡC-Th(Hex)] m [CϡC-Ph-CϡC-Th(Hex)] n containing