Synthesis of an Fe(II) dinuclear triple helicate from a novel -bis-(N-pyrazolyl)pyridine ligand, [Fe 2 L 3 ] 4+ : solution and solid-state studies

Solid- and Solution-State Studies of the

Solid- and Solution-State Studies of the Novel μ-Dicyanamide-Bridged Dinuclear Spin-Crossover System {[(Fe(bztpen)]2[μ-N(CN)2]}(PF6)3⋅n H2O

✍ Norma Ortega-Villar; Amber L. Thompson; M. Carmen Muñoz; Víctor M. Ugalde-Saldív 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 318 KB 👁 1 views

## Abstract The mononuclear diamagnetic compound {Fe(bztpen)[N(CN)~2~]}(PF~6~)CH~3~OH (1) (bztpen = __N__‐benzyl‐__N__,__N__′,__N__′‐tris(2‐pyridylmethyl)ethylenediamine) has been synthesized and its crystal structure studied. Complex 1 can be considered to be the formal precursor of two new dinucl