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Synthesis of an Enantiomerically Pure 1,3-Thiazole-5(4H)-thione and Its Stereoselective 1,3-Dipolar Cycloaddition with an Azomethine Ylide

โœ Scribed by Andreas Gebert; Heinz Heimgartner


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
121 KB
Volume
85
Category
Article
ISSN
0018-019X

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ChemInform Abstract: [2 + 3] Cycloadditi
โœ G. MLOSTON; A. LINDEN; H. HEIMGARTEN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB

## 23 -130 [2 + 3] Cycloadditions of Azomethine Ylides with 1,3-Thiazole-5(4H)thiones. -Azomethine ylides, generated thermally from trans and cis aziridines (I), (VII), (VIII), and (X) give with thiazolethiones (II) in almost all cases mixtures of only two diastereomeric spirocyclic [2 + 3] cycloa