Synthesis of an Asymmetric Fullerene Dimer via Sequential Cycloadditions.
β Scribed by Timothy J. Hingston; Mark R. Sambrook; Nicholas H. Rees; Kyriakos Porfyrakis; G. Andrew D. Briggs
- Book ID
- 102001087
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
An efficient asymmetric synthesis in nine steps of natural (Γ)-pumiliotoxin C (1), a decahydroquinoline alkaloid found in the skin of Central American frog species, is presented. The enantiomerically pure starting material (S)-norvalinol (3), obtained from commercial (S)-norvaline, was cyclized in a