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Synthesis of an Antitumoral Diarylheptanoid Containing 1,3-Diol Functionality

โœ Scribed by Shaomin Zhang; Yikang Wu

Book ID
102096981
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
70 KB
Volume
29
Category
Article
ISSN
0256-7660

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v5+ -Catalyzed t-butylhydroperoxide epoxidation of (Z)-5-hydroxy-2- alkenylsilanes 4 exhibit good to excellent ervthro selectivity. The resulting epoxides undergo fragmentation to afford 1,3-diols 8, albeit in low chemical yield. Many natural products of current interest contain either a 1,3-diol s