An enantiospeci!ic route to jasmonoid natural products, (+) -methyl epijasmonate and (-) -methyl cucmbate from L-glutamic acid is reported. The key step is a 5-(3,4) ene cyclization of a fmxtionahzed 14diene as chiron. which sets up three chin11 centres with a high degree of diastereoselectivity.
โฆ LIBER โฆ
Synthesis of an advanced quinocarcin intermediate from 1-glutamic acid
โ Scribed by Thomas A. Lessen; Donald M. Demko; Steven M. Weinreb
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 221 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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