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Synthesis of Amphiphilic Poly(( R , S )-β-malic acid)- g raft -poly(ε-caprolactone): “Grafting From” and “Grafting Through” Approaches

✍ Scribed by Coulembier, Olivier; Degée, Philippe; Gerbaux, Pascal; Wantier, Pascale; Barbaud, Christel; Flammang, Robert; Guérin, Philippe; Dubois, Philippe

Book ID: 120640353
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 212 KB
Volume: 38
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma047928m

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Synthesis and Micellization Properties of Novel Symmetrical Poly(ε-caprolactone-b-[R,S] β-malic acid-b-ε-caprolactone) Triblock Copolymers

✍ Olivier Coulembier; Philippe Degée; Philippe Dubois 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract Summary: A four‐step strategy to synthesize well‐defined amphiphilic poly(__ε__‐caprolactone‐__b__‐[__R__,__S__] __β__‐malic acid‐__b__‐__ε__‐caprolactone) triblock copolymers [P(CL‐__b__‐MLA‐__b__‐CL)], which combines the anionic polymerization of [__R__,__S__] benzyl __β__‐malolactona