Synthesis of amphiphilic block copolymers via ARGET ATRP using an inexpensive ligand of PMDETA
✍ Scribed by Li, Jian; Chen, Haojie; Mu, Guanmin; Sun, Jianping; Sun, Yilin; Wang, Chenyi; Ren, Qiang; Ji, Junling
- Book ID
- 123518587
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 357 KB
- Volume
- 73
- Category
- Article
- ISSN
- 1381-5148
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## Abstract Block copolymer synthesis via a combination of ATRP and RAFT using click chemistry is reported for the first time. A RAFT agent with a terminal propargyl group (PTTC) was synthesized and was used to polymerize butyl acrylate and gave quantitative monomer conversion. Azide‐terminated p(_
## Abstract Well‐defined amphiphilic PCL‐__b__‐PDMAEMA block copolymers were successfully synthesized by a combination of ATRP and “click” chemistry following either a commutative two‐step procedure or a straightforward one‐pot process using CuBr · 3Bpy as the sole catalyst. Compared to the traditi