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Synthesis of amorphous poly(thioarylene)s via oxidative polymerization of diaryl disulfides

✍ Scribed by Kenji Miyatake; Mitsutoshi Jikei; Kimihisa Yamamoto; Eishun Tsuchida

Book ID
102939243
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
611 KB
Volume
197
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Amorphous poly(thioarylene)s containing a methyl substituent and/or an ether bond in the main chain were prepared via oxidative polymerization of diaryl disulfides using 2,3‐dichloro‐5,6‐dicyanobenzoquinone. The resulting poly(thio‐2,6‐dimethyl‐1,4‐phenyleneoxy‐1,4‐phenylene) having alternating ether and thioether bonds shows a better solvent solubility and has a higher glass transition temperature (T~g~) (182°C) than non‐substituted poly(thio‐1,4‐phenylene). Polymerization of methyl substituted diphenyl ether derivatives with disulfur dichloride has been also developed for a one‐pot synthesis of amorphous poly(thioarylene)s.

📜 SIMILAR VOLUMES

Synthesis and thermal characteristics of
Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization
✍ Eishun Tsuchida; Kimihisa Yamamoto; Kenji Miyatake 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 808 KB

Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high t