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Synthesis of amidopyrine and analgin from methylenbismonomethylaminoantipyrine

โœ Scribed by N. M. Kolgina; A. M. Tsyganova; L. S. Blinova; V. A. Zasosov


Book ID
112398209
Publisher
Springer
Year
1968
Tongue
English
Weight
245 KB
Volume
2
Category
Article
ISSN
0091-150X

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The preparation of (-)-16 from (+)-3 constitutes a formal enuntiospecific synthesis of (-)-bactobotin from D-glucose. The key traasfonnation involves the diustereoselective addition of LiCHCl2 to 7 in the presence of CeC13. The synthesis of (+)-3 from (+)-uctinobolin sulfate is reported and illustra