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Synthesis of .alpha.-thiophene oligomers via 1,3-butadiynes

โœ Scribed by Kagan, Jacques; Arora, Sudershan K.

Book ID
120938675
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
538 KB
Volume
48
Category
Article
ISSN
0022-3263

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The synthesis of alpha-thiophene oligome
The synthesis of alpha-thiophene oligomers via organoboranes
โœ Jacques Kagan; Sudershan K. Arora ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

Oligomers containing from 2 to 6 thiophene units attached by their 2 and 5 positions were synthesized unambiguously by iodine oxidation of a suitable ate complex obtained by stepwise reactions of 9-BBN with methanol, a 2\_lithiothiophene, boron trifluoride etherate, and a second 2-lithiothiophene. T