Synthesis of allylamines in enantiomerically pure form
✍ Scribed by José M Concellón; Beatriz Baragaña; Estela Riego
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 76 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Chiral acetylene dithioethers have been synthesized by the first time in enantiomerically pure form through a high yield (93-100%), one-pot procedure involving the successive treatment of trichloroethylene with three equivalents of lithium bis(trimethylsilyl)amide and two equivalents of a chiral thi
Trans-(2R,3S)-and (2S,3R)-3-phenylglycidic acids were obtained as pure crystals. The optical properties and chemical stability were characterized. The absolute configuration of the trans-(+)and trans-(-) isomers was established by means of chemical correlation.