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Synthesis of allopumiliotoxin A alkaloids via iminium ion-vinylsilane cyclizations

✍ Scribed by Renee M. Lett; Larry E. Overman; Jeffery Zablocki

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 261 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82392-8

No coin nor oath required. For personal study only.

✦ Synopsis

The title reaction can be employed to assemble the allopurniliotoxin A alkaloid skeleton with either stereochemistry of the C-7 allylic hydroxyl group.

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