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Synthesis of alkyl phosphinic acids from silyl phosphonites and alkyl halides

✍ Scribed by E.Andrew Boyd; Andrew C. Regan; Keith James


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
352 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis


Ababmck Mono-and d&substituted phosphinic acids have km synthesti in a one-pot reaction, by the adition of alkyl halides to silyl phosphoaites, w&r mild andflaibk conditions.


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Lithium amides reacted with tellurium under atmospheric pressure of carbon monoxide to yield lithium carbamotelluroates which were trapped with alkyl halides to give Te-alkyl carbamotelluroates in good yields. Results of control experiments suggested that lithium carbamotelluroates were formed by th