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Synthesis of alkyl- or aralkyltrihalogermanes by reaction of trihalogermanes with alcohols

✍ Scribed by O. M. Nefedov; S. P. Kolesnikov; B. L. Perl'mutter


Book ID
112433023
Publisher
Springer
Year
1969
Tongue
English
Weight
281 KB
Volume
18
Category
Article
ISSN
1573-9171

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Treatment of homoallylic alcohols with NaIO 4 /NaHSO 3 reagent in aqueous t-BuOH under mild conditions produced tetrahydrofuran derivatives together with iodohydrins in a stereospecific manner. The reaction pathways of the formation of tetrahydrofurans from trans-and cis-homoallylic alcohols were fo