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Synthesis of alkoxysilyl-terminated polyisoprenes by means of “living” anionic polymerization, 1. Modeling of the termination step by studying the reaction of butyllithium with various alkoxysilane reagents

✍ Scribed by Daniel Derouet; Sylvie Forgeard; Jean-Claude Brosse


Book ID
102663048
Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
748 KB
Volume
199
Category
Article
ISSN
1022-1352

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Synthesis of end-functionalized polymer
✍ Mieko Tohyama; Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 773 KB

## Abstract Anionic living polystyrene and polyisoprene were allowed to react with six __tert__‐butyl‐dimethylsilyl ethers of ω‐halo‐1‐alkanols 1–6, the trimethylsilyl ether of bromohydrin (7), the __tert__‐butyldimethylsilyl ether of 4‐bromophenol (8), and __tert__‐butyldimethylsilyl 3‐chloropropy