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Synthesis of Alkenynyl Vinyl Silanes

✍ Scribed by Gawdzik, Barbara; Saletra, Agnieszka; Wawrzeńczyk, Czeslaw

Book ID
127081682
Publisher
Taylor and Francis Group
Year
1998
Tongue
English
Weight
302 KB
Volume
134
Category
Article
ISSN
1042-6507

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✍ Glenn D. Prestwich; Czesław Wawrzeńczyk 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 246 KB

A general method for the preparation of mixed ally1 vinyl dimethylsilanes uses the sequential coupling of two different alkenylmetallics to (chloromethyl)dimethylchlorosilane. This method is applied to synthesize the 12-dimethylsila analog of squalene. Although both allylsilanes and vinylsilanes ar