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Synthesis of agarofuran antifeedants. Part 6: Enantioselective synthesis of a key decalinic intermediate

✍ Scribed by François-Didier Boyer; Thierry Prangé; Paul-Henri Ducrot

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
216 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

The asymmetric synthesis of a template decalin precursor in the synthesis of polyhydroxylated agarofuran sesquiterpenes is described via a Lewis acid catalysed addition of furan to an activated cyclohexenone directed by an adjacent chiral ketal moiety.

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