Synthesis of two branched heptopyranosid
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G. J. P. H. Boons; M. Overhand; G. A. van der Marel; J. H. van Boom
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Article
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2010
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Elsevier Science
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English
⚖ 563 KB
## Abstract The diastereogenic addition of (phenyldimethylsilyl)magnesium chloride to methyl 3‐__O__‐allyl‐2,4‐di‐__O__‐benzyl‐α‐D‐__manno__‐hexodialdo‐1,5‐pyranoside gave a L‐__glycero__‐D‐__manno__‐heptopyranoside (L,D‐Hep__p__) derivative having at C‐7 the phenyldimethylsilyl function as a hydro