Synthesis of a star-shaped polymer by coordination of 2,2'-bipyridyl-terminated poly(propylene glycol) with ruthenium ion
✍ Scribed by Gen-ichi Konishi; Yoshiki Chujo
- Book ID
- 106002574
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 57 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0170-0839
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## Abstract The star‐shaped polymer with __trans__‐tetrapyridyl complex of Ru(II) as a core was prepared by complexation of ester‐linked pyridyl‐terminated poly(oxyethylene) (__M̄__~n~ = 2000) with a Ru~5~Cl~12~^2−^ cluster. The unimodal peak of the star‐shaped polymer in the gel‐permeation chromat
## Abstract Hydroxy‐terminated telechelic poly(2‐chloroethyl vinyl ether) (poly(CEVE)) was synthesized by water‐based end‐capping reaction of living poly(CEVE) with the initiating system CH~3~CHClOCH~2~CH~2~OCOCH~3~/ZnCl~2~ in CH~2~Cl~2~ at −40°C and subsequent end‐group transformation of the ace