𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of a simple chiral auxiliary derived from levoglucosenone and its application in a Diels–Alder reaction

✍ Scribed by María M. Zanardi; Alejandra G. Suárez


Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
372 KB
Volume
50
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis of a 1,3-spiro-amino-alcohol-d
✍ Susan M. Lait; Masood Parvez; Brian A. Keay 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 277 KB

A short synthesis and resolution of (1R,5R,6R)-6-aminospiro[4.4]nonan-1-ol, 11, is reported. The pivalamide derivative (+)-5 gives excellent diastereo-and regiocontrol as well as endo selectivity as a chiral auxiliary in the BCl 3 -catalyzed Diels-Alder reaction with a variety of symmetrical and uns