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Synthesis of a Series of Organophosphorus Esters Containing Alkylating Groups 1

โœ Scribed by GOLD, ALLEN M.


Book ID
126919887
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
589 KB
Volume
26
Category
Article
ISSN
0022-3263

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Petard oxidation of methyl 2-thialaurate [CH3(CHT.)9--S--COOCH3, 1] gave methyl (decylsulfinyl)formate [CH3(CH2)9--SO---COOCH 3, 2]. Compound 2 reacted spontaneously with silica gel to give decyl decanethiolsolfinate [CH3(CH2)9--SO--S--(CH2)gCH 3, 3] in 84% yield. Thin layer chromatography of carbom