Synthesis of a Selenidostannate(IV), [Mn(tepa)·Sn 3 Se 7 ] n , Demonstrating the Transformation from Achiral to Chiral and Dimeric to Polymeric Structure

Synthesis and Structure of [Sn4Se11]6–,

Synthesis and Structure of [Sn4Se11]6–, 3.0.CO;2-M/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l55r5t&s=b439cdb160594bc76a5be3d9bf20c7c44cb6e3bd" class="inlineGraphic"> [Sn2Se52–], and 3.0.CO;2-M/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l55r5t&s=155c1d4a988fd3c89485d09b17a5955efa65189b" class="inlineGraphic"> [Sn3Se72–] – Model Anions for the Solventothermal Reaction Pathway to Lamellar Selenidostannates(IV)

✍ Anja Loose; William S. Sheldrick 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 2 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re