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Synthesis of a Poly(vinyl alcohol)-Based Graft Copolymer Having Poly(ε-caprolactone) Side Chains by Solution Polymerization

✍ Scribed by Keigo Aoi; Hiromi Aoi; Masahiko Okada


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
327 KB
Volume
203
Category
Article
ISSN
1022-1352

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✍ Zhongyu Li; Guangqiang Lu; Junlian Huang 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 98 KB

## Abstract A novel block copolymer, poly(ε‐caprolactone)‐__b__‐poly(4‐vinyl pyridine), was synthesized with a bifunctional initiator strategy. Poly(ε‐caprolactone) prepolymer with a 2,2,6,6‐tetramethylpiperidinyloxy (TEMPO) end group (PCL~T~) was first obtained by coordination polymerization, whic