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Synthesis of a photoaffinity analogue of phosphatidylinositol 3,4-bisphosphate, an effector in the phosphoinositide 3-kinase signaling pathway

✍ Scribed by Oliver Thum; Jian Chen; Glenn D. Prestwich

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
260 KB
Volume
37
Category
Article
ISSN
0040-4039

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✦ Synopsis

A Ferrier rearrangement strategy starting from S-D-glucose gave a protected inositol, which after coupling to a chiral diacylglycerol phosphoramidite, provided a tritium-labeled, benzophenone-containing derivative of P-l-(O-aminopropyl) linked dipalmitoyl Ptdlns(3,4)Pz.

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