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Synthesis of a Persistent 1σ3,3σ3-Diphosphaallyl Cation Featuring a Localized Phosphorus−Carbon Double Bond

✍ Scribed by David Martin; Antoine Baceiredo; Guy Bertrand


Book ID
102170052
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
119 KB
Volume
2004
Category
Article
ISSN
1434-1948

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First 1-phospha-1,3-dienes unsubstituted
✍ Gonzalo Martin; Edgar Ocando-Mavarez 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 284 KB

## Allylic phosphine systems were studied as phosphorus-carbon double bond precursors. I -Phenyl and Ibutyl-1 -phospha-l,3-dienes were generated by pyrolysis at 350-460°C of the corresponding diallyl phosphines in a stirred-flow reactor. The unsubstituted phosphadienes generated in this manner dim