Synthesis of A-Pentacyclic Triterpeneα,β-Alkenenitriles
✍ Scribed by Pereslavtseva, A. V.; Tolmacheva, I. A.; Slepukhin, P. A.; El’tsov, O. S.; Kucherov, I. I.; Eremin, V. F.; Grishko, V. V.
- Book ID
- 121832953
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 202 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0009-3130
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📜 SIMILAR VOLUMES
In Previous reports' from these laboratories an efficient route to the pentacyclic diether 1 was described. A pentacyclic diaromatic compound of this type, with the trans-anti-trans BCD ring structure and the correct array of angular methyl groups, was envisaged as a useful key intermediate for the
As part of our program to devise a convergent synthesis of pentacyclic triterpenes, e.g., B-amyrin (\_1),1 we have developed an efficient route to the racemic bicyclic enone 2. Compound 2 is a ring AB synthon which may be useful