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Synthesis of a pentacyclic precursor to the Strychnos alkaloids

โœ Scribed by Kraus, George A.; Thomas, P. J.; Bougie, Dan; Chen, Li


Book ID
121226266
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
458 KB
Volume
55
Category
Article
ISSN
0022-3263

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Synthetic indole alkaloids.II. A two ste
โœ Frederick V. Brutcher Jr.; Harry Hinney ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 105 KB

Our recently synthesized' pentacyclic ester lactam(l) represents a central intermediate for preparing, with proper structural variations, reserpinoid and yohimbinoid molecules2 since itsD/E ring junction reduces cis 1 while maintaining an epimerizable C20 hydrogen for possible conversion toD/E trans