Hypervalent pentacoordinate boron compounds (10-B-5) have been postulated as transition states in S N 2-type reactions at a boron atom. For example, the reaction of the [BH 3 -CO] complex with NMe 3 [2] as well as the intramolecular bond switch at the boron atom in compounds bearing a van Koten typ
โฆ LIBER โฆ
Synthesis of a Novel Potential Tridentate Anthracene Ligand, 1,8-Bis(dimethylamino)-9-bromoanthracene, and Its Application as Chelate Ligand for Synthesis of the Corresponding Boron and Palladium Compounds
โ Scribed by Makoto Yamashita; Kumiko Kamura; Yohsuke Yamamoto; Kin-ya Akiba
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 106 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0947-6539
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Hypervalent pentacoordinate boron compounds (10-B-5) [1] have been postulated as transition states in S N 2-type reactions at a boron atom. For example, the reaction of the [BH 3 -CO] complex with NMe 3 [2] as well as the intramolecular bond switch at the boron atom in compounds bearing a van Koten