𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of a novel azobenzene-based trihydroxamate siderophore and photoregulation of its ferric complex structure

✍ Scribed by Takeshi Masuda; Sayaka Asari; Seizo Tamagaki; Takeshi Nagasaki

Book ID
104210057
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
157 KB
Volume
41
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

In order to develop an artificial photoresponsive siderophore by utilizing the photo-isomerization of an azobenzene group, a novel trihydroxamate siderophore based on an azobenzene skeleton was synthesized. The 1:1 and 2:2 stoichiometry of the ferric complex can be almost perfectly regulated reversibly by irradiation with UV and visible light, respectively.

πŸ“œ SIMILAR VOLUMES

Synthesis and crystal structure of a nov
Synthesis and crystal structure of a novel triangular macrocyclic molecule, tris(H2saloph), and its water complex
✍ Shigehisa Akine; Takanori Taniguchi; Tatsuya Nabeshima πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 106 KB

Condensation of 2,3-dihydroxybenzene-1,4-dicarbaldehyde and 1,2-phenylenediamine afforded a novel 30-membered macrocyclic hexaimine bearing six hydroxyl groups, in which a water molecule is trapped in the crystalline state.