Synthesis of a new stable peristatic chiral pseudocryptand for simultaneous binding of boron and sodium

✍ Scribed by Mahmut Toǧrul; Halil Hoşgören; Giray Topal; Mürüvvet Yurdakoç

• Book ID: 102344899
• Publisher: Journal of Heterocyclic Chemistry
• Year: 2005
• Tongue: English
• Weight: 109 KB
• Volume: 42
• Category: Article
• ISSN: 0022-152X
• DOI: 10.1002/jhet.5570420626

✦ Synopsis

A new selective molecular receptor, borocryptate, based on the combination of the 15 membered ring diazatrioxa core and two saligenin units as binding sites for boron has been described. The resulting peristatic chiral compound is stable in air and easily converted to polynuclear complex, Na-borocryptate, without using an inert atmosphere.