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Synthesis of a new poly(carboxybetaine) with peptide main chain

โœ Scribed by Jiro Nagaya; Hirotaka Uzawa; Norihiko Minoura

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
55 KB
Volume
20
Category
Article
ISSN
1022-1336

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โœฆ Synopsis

A new poly(carboxybetaine) whose main chain is composed of peptide bonds was synthesized from poly(c-methyl L-glutamate). The side chains of poly(c-methyl L-glutamate) were exchanged to carboxybetaine structures by three reactions. Our new poly(carboxybetaine) has 84% carboxybetaine structures in the side chains, as determined by 1 H NMR measurements. The presence of betaine structures in the side chains was confirmed by viscosity measurements.

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