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Synthesis of a new octanitroporphyrin: 5,10,15,20-tetrakis(2',6'-dinitro-3',5'-di- tert -butylphenyl)ironporphyrin

✍ Scribed by Rose, Eric; Andrioletti, Bruno; Pandian, Ramasamy P.


Book ID
121729727
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
475 KB
Volume
06
Category
Article
ISSN
1088-4246

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A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at Γ΅ 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the